PETPTT共聚酯的热降解行为.pdfVIP

第34卷第5期 东华大学学报(自然科学版) V01．34，No．5 OFDoNGHUA 2008年10月JoURNAL UNIVERSlTY(NATURALSCIENCE)Oct．2008 文章编号：1671—0444(2008)05—0534—06 PET—PTT共聚酯的热降解行为 方王平，杨胜林，李 光，江建明 (东华大学纤维材料改性国家重点实验室，上海201620) 捅 共聚酯及均聚物的裂解产物的结构及分布，探讨Prr降解机理，并推测PET—P1T共聚酯的可能降解过程．发现 PET—Pn共聚酯分解过程中产生了不同于PET和P丌裂解产物的组分，但不同组分的含量很小，这可能是由共聚 物．当P兀’(PET)在共聚酯中的摩尔分数增大时由该链段降解产生的产物质量分数相应提高． 关键词：PET—Prr共聚酯；聚对苯二甲酸乙二醇酯(PET)；聚对苯二甲酸丙二醇酯(y盯)；裂解气相质谱 中图分类号：TQ050．4+25文献标志码：A Thermal of DegradationPoly(ethylene-- CO—trimethyleneterephthalate)StudiedbyPy—GO／MS FANG IANG Wang-ping，YANGSheng-lin，LJGuang，JJian-ming LaboratoryforModificationofChemical (StateKey FibersPolymerMaterials，VonghtlaUniversity，Shanghai201620，China) Abstract：The behaviorof degradation poly(ethylene-co-trimethylene meansofTGAand andtheresultswere withthoseofPETandmIt by Py—GC／MS investigated compared hasbeenfoundfromTGAthatthe ofPET—mwasintervenientbetweenPErandm．and thermostability withthe PET The distributionandmolecularstructureof improved increasingcomponent． gaseouspyrolysis of andPrTwereobtainedfrom onthe PET—PIvh．PET products Py一0C／MBaseddegradation ofPEr．the ofthe ofPITandPE_r—PTT weredescribed．Itwasfound processesdegradation copolyesters PTT differentfrombothPETand inthe would inthe ．something homopolymersyieldeddegradation present