氯盐_硫酸盐作用下高性能混凝土损伤研究.pdf

氯盐、硫酸盐作用下高性能混凝土损伤研究 金祖权 　孙 　伟 　张云升 　赖建中 (东南大学 材料科学与工程系 　南京 　210096) 　　摘 　要 : 通过 35 %NaCl 溶液 ,5 %Na S0 溶液以及 35 %NaCl + 5 %Na SO 复合溶液的浸泡腐蚀试验 ,研 2 4 2 4 究了 C30 、C50 两种强度等级 ,三种大掺量矿物掺合料混凝土在腐蚀溶液中的自由氯离子扩散规律 , 以及基于 相对动弹性模量变化的损伤规律。结果表明 :复合腐蚀下 ,C30 的自由氯离子含量是 C50 的2 倍左右 ;氯离子 扩散系数为 C50 的 17～195 倍 ;混凝土相对动弹性模量先上升后下降。矿物掺合料提高了混凝土抗氯离子 渗透和抗硫酸盐损伤能力 ,硫酸盐降低了混凝土抗氯离子腐蚀能力 ,氯盐减缓了硫酸盐对混凝土的损伤速 度。 　　关键词 : 混凝土 　硫酸盐 　氯盐 　相对动弹性模量 STUDY ON DAMAGE OF HPC UNDER THE CORROSION OF CHLORIDE AND SULFATE Jin Zuquan 　Sun Wei 　Zhang Yunsheng 　Lai Jianzhong (Department of Materials Science and Engineering ,Southeast University　Nanjing 　210096) Abstract : Based on taking corrosion test of concrete immersed in 35 % weight of NaCl , 5 % weight of Na SO and 2 4 ( ) compound solutions 35 % NaCl + 5 %Na SO ,it has been studied that the free chloride diffusion and mechanical damage , 2 4 based on relative Young′s modulus ,of concrete that include two grades of strength and three types of mineral admixture. The results suggest that the free chloride content of C30 should be 2 times that of C50 ,and free chloride diffusion coefficients be 17～195 times. Moreover ,the mineral admixtures may improve chloride and sulfate ion resistance capacity of concrete ,and the sulfate decreases chloride resistance capacity of concrete ,as well as the chloride decreases the sulfate′s damage speed of concrete. Keywords : concrete 　sul