温度对Q235钢在大港模拟溶液中腐蚀行为的影响.pdf

29 4 Vol. 29 No. 4 2008 4 CORROSION PROTECTION April 2008 试验研究 Q235 , , ( , 100083) : (EIS) Q235 : 20~ 50 , , , , Q235 , , R p R t , Q235 : ; ; ; : T G 172. 6 : A : 1005748X(2008) Corrosion of Q235 in Dagang Simulated Solution at Different Temperatures NIE Xiang ui, DU Cuiw ei, LI Xiaogang ( Center of Corrosion and Protection, University of Science and Tec nology Beijing, Beijing 100083, C ina) Abstract: T e corrosion of Q235 in Dagang simulated solution at different temperatures w as studied by means of polarizat ion curves, linear polarization and EIS. In t e range of 20- 50 , t e corrosion potential was close to t e equilibrium potent ial of t e anodic reaction. Corrosion process w as controlled by t e oxygen transmission of t e cat odic process. W en t e temperature w as elevat ed, corrosion current densit y I corr increased, t e linear polarizat ion resistance R p and t e c arge transfer resistance R t reduced, and t e corrosion rate increased primarily by t e increasing of t e transmission of reactant in t e cat odic process. Key words: temperature; polarizat ion curve; EIS; corrosion potential - 0. 85V ( CSE/ ) 0 , - 0. 85V ( CSE) , 80 , : , - 1. 346V( CSE) pH , Q235 , , , , Q235 , ( , , ) : 0. 14 C, 0. 13 Si, 0. 44 Mn, 0. 015 P, 0. 031 S, [ 1] [ 2] Fe, JungGuKim - 2- - , : Cl SO4