CaO改性对CuZnAlZr催化剂在合成气制低碳醇中性能的影响.pdfVIP

物理化学学~(WuliHuaxueXuebao) June Acta尸 ．一Chim．Sin．2012，28(6)，1461—1466 1461 [Article] doi：10．3866／PKU．WHXB201203302 www．whxb．pku．edu．cn CaO改性对CuZnA亿r催化剂在合成气制低碳醇中性能的影响 朱秋锋 张荣俊 贺德华 (清华大学化学系，有机光电子与分子工程教育部重点实验室，分子催化与定向转化研究室，北京 100084) 摘要： 采用机械混合法和共沉淀法制备了CaO改性CuZnAlZr氧化物催化剂．在高压微型固定床反应器上考 察了其在合成气制低碳醇反应中的催化性能，利用粉末X射线衍射(XRD)、低温氮气吸附一脱附、H程序升温还 原(H一TPR)和二氧化碳吸附．脱附(co TPD)等技术对催化剂进行了表征．结果显示：CaO改性对CuZnAIZr催 化剂的织构性质没有明显的影响：但共沉淀法制备的CaO改性CuZnAIZr催化剂具有弱碱性和中等强度两种 碱性中心，且有较多的碱中心数量：而未改性的CuZnAlZr催化剂只具有弱碱性中心．CO加氢反应结果表明： 经共沉淀法制备的CaO改性CuZnAIZr催化剂对 C+醇的生成有明显的促进作用． 关键词：CaO改性；CuZnAIZr催化剂：合成气：低碳醇 中图分类号：0643 EffectofCaOModificationonPerformanceofCuZnAIZrCatalystin SynthesisofHigherAlcoholsfrom SynthesisGas ZHUQiu—Feng ZHANG Rong—Jun HEDe—Hua (InnovativeCata sisProgram．KeyLaboratoryofOrganicOptoelectronicsandMolecularEngineeringofMintryofEducation， DepartmentofChemistry,TsinghuaUniversity,Bejiing100084, R．China1 Abstract： Ca0 modified CuZnAIZrmixedoxide catalystswere prepared by mechanicaImaxmg and CO-precipitationmethods，andtheircatalyticperformancesforCO hydrogenationtohigheralcoholswere investigated using a continuous flow high．．pressure fixed．．bed micro．．reactor~The catalysts were characterizedbyX-raydiffraction(XRD)，N2一adsorption-desorpotion，temperature-programmedreductionof H2(H2一TPR)，andtemperature-programmeddesorptionofCO2(C02-TPD)．Theresultsshowedthatdoping with CaO did notalterthe texturalpropertiesofthe catalyst，butincreased thenumberofbasic sites． Furthermore，theCaO-modifiedCuZnAIZrcatalystspossessed both weak and medium strength basic sites。while unmodified CuZnAlZr catalystpossessed onlyweak basic sites．Catalyti