新型碱性离子液体催化酯交换合成生物柴油.pdfVIP

第42卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.2 2014年2月 Journal of Fuel Chemistry and Technology Feb. 2014 文章编号:0253鄄2409(2014)02鄄0200鄄07 新型碱性离子液体催化酯交换合成生物柴油 左同梅,李为民,赵摇 强,徐庆瑞,陈摇 诚,陈摇 龙 (常州大学 石油化工学院,江苏 常州摇 213164) 1 摘摇 要:两步法合成了吗啉阴离子型碱性离子液体1鄄丁基鄄3鄄甲基吗啉盐[Hnmm]Im,经 H鄄NMR 和FT鄄IR分析确认了离子 液体中间体的结构,并通过阴离子交换得到碱性离子液体,对该离子液体在酯交换制备生物柴油反应中的催化性能进行了研 究。 结果表明,该碱性离子液体[Hnmm]Im具有较高的酯交换催化活性,在60 益、催化剂用量为3%、醇油物质的量比为 6.5颐1.0、反应2h 的条件下,产物脂肪酸甲酯(FAME)含量可达95.80%。 而且该离子液体的催化稳定性较好,重复使用5次 后仍有较高的催化活性。 关键词:离子液体;酯交换;生物柴油;催化活性 中图分类号:TQ644.2摇 摇 文献标识码:A Synthesis of biodiesel through catalyzed by a novel transesterification alkaline ionic liquid ZUO Tong鄄mei,LI Wei鄄min,ZHAO Qiang,XU Qing鄄rui,CHEN Cheng,CHEN Long (School of Petro ChemicalEngineering,Changzhou University,Changzhou摇 213164,China) Abstract:A novel basic ionic liquid paired by 1鄄butyl鄄3鄄methyl鄄morpholine cation and morpholine anion 1 ([Hnmm]Im) wassynthesizedin two steps;the structure of ionic liquidintermediateswascharacterizedby H鄄 NMR and FT鄄IR. The alkaline ionic liquid was obtained through anion exchange and used as catalyst in the synthesis of biodiesel by transesterification. The results showed that the alkaline ionic liquid [Hnmm]Im is highly active asacatalystinthetransesterification;undertheoptimumreactionconditionsof60益,[Hnmm]Im amount of3%,and methanol/ oil mol ratio of6.5颐1.0,the content of fatty acid methyl ester (FAME) in the productreaches95.80% afterreactionfor2h. Moreover,thealkalineionicliquidexhibitshigh catalytic stability upon reusage;it remainshighly active even after being reused for five times. Key words