纳米孔碳负载Fe3O4催化剂上苯直接羟基化制苯酚.pdfVIP

2011 Chinese Journal of Catalysis Vol. 32 No. 2 Article ID: 0253-9837(2011)02-0258-06 DOI: 10.1016/S1872-2067(10)60173-8 Article: 258–263 Direct Hydroxylation of Benzene to Phenol over Fe O Supported 3 4 on Nanoporous Carbon 1 1,* 1 2 Pezhman ARAB , Alireza BADIEI , Amir KOOLIVAND , Ghodsi MOHAMMADI ZIARANI 1School of Chemistry, College of Science, University of Tehran, Tehran, Iran 2Department of Chemistry, Faculty of Science, Alzahra University, Iran Abstract: Fe O /CMK-3 was prepared by impregnation and used as a catalyst for the direct hydroxylation of benzene to phenol with hydro- 3 4 gen peroxide. The iron species in the prepared catalyst was Fe O because of the partial reduction of iron(III) to iron(II) on the surface of 3 4 CMK-3. The high catalytic activity of the catalyst arises from the formation of Fe O on the surface of CMK-3 and the high selectivity for 3 4 phenol is attributed to the consumption of excess hydroxyl radicals by CMK-3. The effect of temperature, reaction time, volume of H O , and