_Cr_III_SSA_en_2_2H_2O配合物的合成_表征与性质研究.pdfVIP

2006 64 Vol. 64, 2006 9 , 917922 ACTA CHIMICA SINICA No. 9, 917922 · · [Cr(III)(SSA)(en) ]•2H O 2 2 * ( 030006) (III) . (III) [Cr(SSA)(en) ]•2H O (SSA 5-, en), X 2 2 . pH 7.4, 0.05 mol•L1 Tris-HCl , 4 . , (2.7 0.1) 10 mol•L1, 3.87. pH 7.4, 0.05 mol•L1 Tris-HCl , EDTA , 37 0.0142 0.0225 h1. (III); 5-; ; ; Synthesis, Characterization and Properties of Chromium(III) Complex [Cr(III)(SSA)(en) ]•2H O 2 2 LIU, Bin LI, Ying-Qi YANG, Bin-Sheng* (Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education of China, Institute of Molecular Science, Shanxi University, Taiyuan 030006) Abstract In this paper new chromium(III) complex [Cr(SSA)(en) ]•2H O (en ethylenediamine, SSA 2 2 5-sulfosalicylic acid) was synthesized and characterized by elemental analysis, IR, UV-Vis and X-ray crystallography. The interaction of human serum albumin with the complex was investigated by 4 fluorescence spectra, the conditional binding constant K (2.7 0.1) 10 and the number of binding sites n 3 (3.87) were obtained. The kinetic