QCM amp EQCM - 科学院长春应用化学研究所.pptVIP

QCM EQCM - Principle Application in Ion Transport * State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Resonance Standing Wave Standing Wave - A wave characterized by lack of vibration at certain points, between which areas of maximum vibration occur periodically. Resonance - The increase in amplitude of oscillation of an electric or mechanical system exposed to a periodic force whose frequency is equal or very close to the natural undamped frequency of the system. External Stumili External Stumili Quartz Adsorbed Layer dq ? da ?a ?q f0 ?q fm fm – final or total frequency that we measured f0 – intrinsic frequency of quartz crystal dq – thickness of quartz crystal ?q – velocity in crystal of wave transfer ?q – density of quartz crystal ?a – density of adsorbed layer ? da – thickness of adsorbed layer Area=A External Stumili Quartz Adsorbed Layer dq ? da ?a ?q f0 ?q fm Area=A Minute Change in Mass Constant f0 Sauerbrey,s equation, ?f = -2?mf02/A(??)1/2 where ? m is the mass change of quartz crystal surface, ? f is the frequency change caused by ? m, f0 is the fundamental resonant frequency of quartz crystal in the absence of the deposited mass, A is the geometric area of electrode, ? is the shear modulus of quartz and ? is the density of quartz. ? f = C? m C is called as calibration constant of QCM Ref : Sauerbrey, G. Z. Phys. 1959, 155, 206. Quartz Crystal Metal Electrode Front Lead Wire Back Lead Wire Illustration of quartz crystal oscillator The shearing stationary wave in quartz crystal and its propagation AT-Quartz Displacement y x hf Surface Mass Layer ?f, ?f Liquid ?, ? Ref.: S. Bruckenstein, M. Shay, Electrochim. Acta, 30(1985)1295. S. Bruckenstein, S. Swathnaian, Electrochim. Acta, 30(1985)851. Illustration of EQCM instrument Regulator Working Oscillator Potentiostat W R C f Counter Cell I, V, t f Illustration of Time-resolved EQCM Refer