第4章 合营物(国外英文资料).docVIP

第4章 配合物 Chapter 4 complex Design some experiments to show that the yellow of crude hydrochloric acid is Fe3 + and Cl - instead of iron hydronium or hydroxycation. 9-2 FeF63-6 ligand, and FeCl4-4 ligand, how do you explain? Solution: the fluorine ion is small, the chloride ion is large. 9-3 MA3B3 ﹑ MA2B4, MABC4, MA2B2C2, MABCDEF (M on behalf of the central atom, other letters on behalf of the ligand) each may have several stereoisomers (including geometrical heterogeneous and antipodal heterogeneous)? Is there any isomer for the combination of 9-4, hexaploid and octahedron? Solution: 1 pair enantiomers. Why is it that the hydrolytic product of the hydrolysis of cisplatin, Pt (OH) 2, can react with oxalic acid to produce the Pt (NH3) C2O4, but not the geometric isomer? Which isomers are polar and non-polar? Which water is more soluble? Solution: the carbon chain of a double tooth ligand is very short, and it is impossible to match a bit. The type is large and water-soluble. 9-6 Werner, founder of the coordination chemistry, found that the amount of substance such as yellow CoCl3.6 NH3, amaranth CoCl3.5 NH3, green CoCl3.4 NH3 and purple CoCl3.4 NH3 four complexes is soluble in water, to join the silver nitrate, immediately the precipitation of silver chloride respectively, 3, 2, 1, 1 mol, please according to the experimental facts to infer that they contain the composition of complex ion. It is possible to determine the number of ions ionized by electrolyte in solution, and the number of ions is positively correlated with the size of the conductance. What is the quantitative relationship between the electrical conductance of these four complexes? The solution: [Co (NH3) 4 (H2O) 3 +; [NH3] 4. (NH3) [c] (NH3) + [Co (H2O) 2Cl4] The 9-7 experiments were measured in Fe (CN) 64 - and Co (NH3) 63 + all of which were anti-magnetic material (magnetic moment equals zero), and asked their hybrid orbital type. 7, solution: d2sp3; d2sp3 How many stereoisomers are there in each of