第四章 合营物(国外英文资料).docVIP

第四章 配合物 Chapter 9 complex 9-1: distinguish the following concepts (a) ligands and complexes, (b) external and inner rail complexes, (c) high spin complexes and low spin complexes, (d) a strong ligand and a weak field ligand, (e) geometric and optical isomerism, (f) active complexes and inert complexes, (g) to generate constant and step by step, (h) chelation effect and counterposition effect. A: A: (a) a molecule or ion that is combined with a central atom or ion in an entity called a ligand. The chemical species that combine the body and the body (with the individual) are the complexes. More broadly, the combination of lewis acid and lewis base. (b) on the complexes of valence bond theory, all coordination atoms lone pair electrons to fill in the center of the atoms, or ions by the outer d orbital hybridization and hybrid orbitals, form the coordination bond complexes is the outer rail complexes. Instead, fill in the hybridized orbital that is involved in the inner layer (n-1) d, which is the inner track. (c) from the crystal field theory of complexes, due to the relative size and Δ 0 P, makes complexes may have two different arrangement of the electrons in the configuration, it contains more single electron complexes is called high spin complexes, there is no single electron or less complexes containing a single electron Numbers called low spin complexes. (d) when the ligands and the central metals are matched, the ligands and the ligands are strong and weak due to the dissociation of the ligands In the following order: I - Br - Cl - - - The ligand in the front of the sequence (mostly H2O) is called a weak field ligand, and the ligand in the back of the sequence (which is generally called an NH3) is called a strong ligand. (e) the isomers of the complexes. Ligands around the central atom with different arrangement of heterogeneous phenomenon, known as the geometry