不同晶型纳米CdS的合成与其光催化活性.pdfVIP

20 2 2009 6 CH EM ICAL RESEARCH hxyj @ henu. edu. cn CdS * 丁优仙, 于迎春, 刘建军 , 左胜利 (, 100029) : , , , /, CdS. n ( S) /n( Cd) = 0. 5~ 3, CdS( n( S) /n ( Cd) = 0. 5) , (n ( S) /n ( Cd) = 1. 0~ 1. 5), (n ( S) /n( Cd) \ 2). XRD, TEM, UV-V is, IR CdS, , , , . B, CdS ( + ), CdS ( 10~ 13 nm ), B. : ; ; ; ; ; ; B : O 612. 4 : A : 1008- 1011( 2009) 02- 0012- 05 Synthesis and Photocatalytic A ctivity of Cadm ium Sulfide w ith D ifferent Crystal Structures * DING You-xian, YU Y ing-chun, LIU Jian-jun , ZUO Sheng-li (Faculty of Science, B eij ing University of Chem icalTechnology, B eij ing 100029, Ch ina) Ab stract: The cadm ium su lfide (CdS) crystals w ere synthesized via a comp lex compound thermolysis m ethod w ith d ifferent molar ratio of thiourea to acetate cadm ium (S /Cd). The as-synthesized CdS sam- ples are of cub ic phase, m ixed phase of cub ic and hexagonal, and hexagonal phase w hile ( n ( S) /n (Cd) ) are equal to 0. 5, 1. 0~ 1. 5, \2, respectively. The phase composition, particle morphology and size, absorbance and surface structures of CdS w ere characterized by XRD, TEM, UV-V is and IR spectra. The results of photocatalytic degradation to rhodam ine B (RB) show that the activity orders of CdS concerning the phase compositions are cub ic hexagonal cub ic+ hexagonal, where the cubic phase ofCdS has the best photocatalytic degradation activity toRB because of its larger adsorption abi-l ity and absorban