新型三嗪类氮-硅成炭剂的合成及其热稳定性.pdfVIP

学兔兔 2015年第23卷 合成化学 Vo1．23，2015 第1期，27—30 Chinese Journal of Synthetic Chemistry No．1．27—3O · 研究论文· 新型三嗪类氮．硅成炭剂的合成及其热稳定性 刘胜男，赵培华，李欣航，梁文俊，刘亚青 (中北大学材料科学与工程学院山西省高分子复合材料技术研究中心，山西太原 030051) 摘要：以三聚氯氰(1)和’，一氨丙基三乙氧基硅烷(2)为原料，经亲核取代反应合成了一种新型三嗪类氮罐成炭 剂——_2-氯4，6-二(3-三乙氧基硅烷基-1一氨丙基)-1，3，5-三嗪(3)，其结构和热性能经。H NMR，IR和TGA表 征。考察了溶剂、缚酸剂、原料比和反应温度对3产率的影响。合成3的最佳反应条件为：以丙酮为溶剂， Na2CO，为缚酸剂，1 10 mmol，rI(2)：，I(1)=2．4，于5O qC反应6 h，产率98．1％。3的初始分解温度为292℃。 70o℃时成炭率34．5％。 关 键 词：三嗪类成炭剂；氮一硅成炭剂；合成；热稳定性 中图分类号：0626．43；0621．3 文献标识码：A DOI：10．15952／j．cnki．cj8c．1005—1511．2015．01．0027 Synthesis and Thermal Stability of a Novel Triazine-based N——Si Charring Agent LIU Sheng—rlarl，ZHAO Pei—hua，LI Xin—hang， LIANG Wen-jun，LIU Ya—qing (Research Center for Engineering Technology of Polymeric Composites of Shanxi Province， School of Materials Science and Engineering，North University of China，Talyuan 030051，China) Abstract：A novel triazine—based N—Si charring agent，2-chloro-4，6一di(3-triethoxysiloxy一1-aminopro— py1)一1，3，5-triazine(3)，was synthesized by nucleophilic substitution reaction of cyanuric chloride (1)with(3一aminopropy1)triethoxysilane(2)．The structure and thermal property were characterized by H NMR，IR and TGA．Effects of solvent，acid—blinding agent，molar ratio of raw materials and reaction temperature on the yield of 3 were investigated．The yield of 3 was 98．1％ under optimal re— action conditions[acetone WaS solvent，Na2CO3 WaS acid·blinding agent，1 was 10 mmol，n(2)：n (1)was 2．4，at 50℃for 6 h]．Initial decomposition temperature of 3 was 292℃，and the char yield is about 34．5％ at 700 oC． Keywords