氰根桥联3d-4f配合物分子磁体的磁性研究.pdfVIP

M a g n e tic P ro P e rti e s o f m o le e u la r m a g n e ts b a se d o n 3 d 一4 f c o m P lex s b y ey a n id e lig a n d P o stg ra d u a te :M 厄n g L in a 介 tor :P ro f.L ian g F u P e i，P ro f.Yu n H e S P ee ia lty :At om ie an d M o leeu lar P h y sies D ir ee tio n :M o ssb au er in th e 叩 P lieatio n o f so lid m ate ria ls G ra d e :2 0 0 7 A b st邝 C t C y an o 一b rid g e d eo mP lex e s h av e b e en w id e ly stu d ied in m an y f ie ld s ，P art icu larly h av e sh o w n m agn etie ProPerties w ith h igh T e values and m agn etie一oPtical Phenom enon . Th ese stud ies w ere m a in ly foe u s o n tran sitio n m e ta ls . U n til r ee en tly ，the stu d ie s a b o u t m a gn e tie P ro P er tie s o f 3 d 一4 f m o lecu lar com P lexes are very scarce.T h e m ajor diffieu lties in studying the m agnetie ProPerties of the 3 d 一4 f m o le eu lar e o mP lex e s arise fro m th e w e ll一sh ie ld e d 4 f e le ctro n s o f ra re e ar th io n s ， ex e eP t ror o d 3+ ，h a s a 斤ist一o rd e r an 即 lar m o m enut m ，w h ieh p rev en ts th e u se o f a sp in 一o n xy H am ilton ian ror isotroP ic ex ehan ge.T he jo int effe et of the eleetrostat ie crystal field an d orbital com tribution ean resu lt in an im P o rat n t an iso tr0P y o f th e m a gn etie su seeP tib ility an d ex ch an ge in ieract io n . R ecen tly， U sin g b etain e，N ，N 一d im ethy lform am ide (D M F ) as hybrid ligand ，m an y 3d一4f C yan o一bridged e o mP lex e s h av e b e e n sy n the siz e d an d the ery stal stur ctu re s a n d m a g n etie