水浴法制备ZnO微纳米结构.pdfVIP

Abstract Abstract Nanomaterials have some physical and chemical properties different from the bulk materials, which makes the nano-materials as the most promising materials in the present. ZnO, with a wide direct band gap (3.37 eV), is a II-VI group metal oxide semicondutor. Compared with other wide bandgap semiconductor materials, ZnO has a high exciton binding energy, which is 60 meV at room temperature. ZnO is a n-type semiconductor, so it is often applied in photoelectric. Besides, ZnO micro/nano structure also has excellent properties in cathode field emission and photocatalytic. There are many methods to synthesize ZnO nano/micro structures, but some of them are intrict in the synthese instruments, and the controllability in the growth of ZnO nano/micro structures is not sufficient. In this paper, for realizing the controllable growth of ZnO nano/micro structures, a simple chemical water bath method was used to prepare ZnO nano/micro stuctures. The specific content of this paper is as follows: (1) We studied the morphology of products which was producted in the growth process of ZnO micro/nano structure under the condition of different water bath temperatures with the method of multiple containers, and the influence of annealing on the morphology of products. The results showed that when the temperatures of water bath were different, the morphology of products were different ;After annealing, the crystal quality of the products had been improved. (2) ZnO micro/nano structure was synthesized