港口矿石堆场重金属对渤海湾潜在污染风险评价.pdfVIP

ABSTRACT At present, the ore stacked in Tianjin Port is mainly deposited in the open air, the leaching of rain will cause the dissolution of heavy metals in the ore . Static soaking and dynamic leaching experiments showed that the dissolution amount of some elements exceeded the standard. In this study, microcosm and mathematical mode l were builded in order to analysis and simulate the aquatic environment, to explore the migration behavior of heavy metals in aquatic environment, to get the inherent law. Simultane ously, the work, detecting the total content and fraction of heavy metals and physicochemical indexes in the surface sediment of Bohai Bay, was carried out in order to know the impact of ore stacking yard of Tianjin Port on Bohai Bay, to provide data and theory to prevent Bohai Bay from being polluted by heavy metal. A series of results and viewpoints were presented: (1) In aquatic microcosm, the concentration of lead and cadmium in the water phase firstly increased and then decreased , and the content of lead declined faster than cadmium. The concentration of cadmium in the sediments increased slowly within 120 h, and then fell slightly. The concentration of lead in the sediments increased rapidly within 24 h, and then fluctuated slightly. The increase of total content of cadmium was mainly caused by the increase of exchangeable form amd fractions bound to carbonates and Fe/Mn-oxides in the sediments. The increase of total content of lead was mainly caused by the increase of fractions bound to carbonates, Fe/Mn-oxides and organic matter. (2) That the simulated results matched the data obtained by the experiment well