聚乳酸结晶、熔融行为以及无序—有序相转变.pdfVIP

A B S T R A C T P oly (laetie aeid) (P L A ) 15 a b iodegradab le P lastie that ean be Produeed from ren ew ab le so ur ee s， su eh a s e o m . P L A h as b een u sed in P a ek in g an d m ed iea l aP P lieatio n su ee e ssfu lly . B u t th e ery sta llizatio n rat e o f P L A 15 v ery sm a ll，an d un d er u su a l P ro ee ss eo n d itio n o n ly ean g et am o rph o u s P 叭 5. 5 0 the u se o f P L A in the d o m a in th at re q u ire re sistan ee o f h ig h tem P eratur e 15 lim ited . In th is th e sis，tw o strate g ie s to P ro m o te P L A ery stallizatio n w ere inv e stig ated . O n e 15 thr o u g h th e m ethod of m odifying to advan ee the erystallize rate of P L A .An other 15 ann ealing am o rph o u s P L A . In the asPect of P L A m odifying，this thesis studied the influenee toh tale (nueleating agenis) an d Poly (ethylene glyeol)(P E G )(Plastieizers) on ery sta lliza tio n behavior of P LA . W 己u se diffe rential seann ing ealorim etry (D SC ) study the non一isotherm alerystallization behav ior of PLA before and after m odifying， an d fin d o ut that at the sam e eo o lin g rate ery sta llizatio n en th a lP y o f m o d ified P L A 15 m u ch larg er an d the h a lf ery sta llizatio n tim e o f m o d ifie d P L A 15 m u eh sm a ller th an P L A . T h e ir cry sta llizatio n b eh av io rs un d er d iffe rent eo o lin g rate we re an a ly z ed b y thr ee n o n 一iso therm a l ery sta llizatio n k in etie s m o d e l. It w a s foun d th a t Jez io m y eq u atio n ， O zaw a e q u atio n an d M o eq u atio n w ere all su it th em ， an d ery sta llizatio n k in etie s P aram eters w ere fig u red o ut o n th