Ni(NO3)2浓度对Ni还原氧化石墨微观结构及微波吸收性能的影响.pdfVIP

第 31 卷第 I1 期 Vo l. 31 No. 11 无机材料学报 2016 年 II 月 Joumal of Inorganic Materials Nov. , 2016 文章编号: 1000-324X(20 16) 11-1223-07 DOI: IO .l5541/ji Ni(N0 )2 浓度对NiI还原氧化石墨微观结构 3 及微波吸收性能的影晌 祝海，杨丽，刘洪波，陈惠，夏笑虹 (湖南大学材料科学与工程学院，长沙 410082) 摘要:以Ni(NÛ3)2 为 Ni 源，利用液相浸溃法在氧化石墨层间吸附Nih，通过民热还原制备出Ni/还原氧化石墨纳 米复合材料。采用扫描电子显微镜(SEM)、 X 射线衍射仪(XRD)及网络矢量分析仪等对样品的结构及性能进行分析 和表征，研究了 Ni(NÛ3h 浓度对材料微观形貌及电磁性能的影响。结果表明，所制备材料为纳米级Ni 颗粒与 RGû 的复合体，具有优良的微波吸收性能; 当 Ni(NÛ3)2 浓度为1.5 moVL 时，材料电磁吸收性能最佳，在2-18 GHz频率 范围内，材料厚度为 2mm 时，反射损耗(RL)小于-5 dB 的频率范围可达9 GHz， RLma:.可达-40dB。 关键词:Ni; 氧化石墨i 纳米复合材料i 微波吸收 中图分类号: TB333 文献标识码:A Effect ofNickel Nitrate Concentration on Microstructure and Microwave Absorbing Property of NilRGO Nanocomposite Material ZHU Hai , YANG Li, LIU Hong-Bo , CHEN Hui , XIA Xiao-Hong (C创lege of Material Science and Engineeri吨， Hunan University, Changsha 410082 , China) Abstra ct: A technique for obtaining reduced graphite oxide (RGO) with Ni nanoparticle dispersed on the surface via chemical vapor deposition (CVD) method was reported. XRD and SEM observations were carried out ωconfmn the microstructure of NνRGO composite. Magnetic property of Ni/RGO was characterized by vector network analyzer. The influence of Ni (N03)2 concentration on micromorphology and microwave absorbing property were also discussed. As the concentration ofNi(N03h is 1.5 mo且， the range ofthe reflection loss (RL) less than -5 dB is 9 GHz, ofwhich them献value reaches -40 础， Key words: nickel; graphite oxide; nanocomposite material; microwave absorbing