NiC催化剂上山梨醇氢解反应中碱对乳酸形成的影响.pdfVIP

Chinese Journal ofCata lys is 37 (2016) 177-183 催化学报 2016年第37卷第1期 1 available at www . .· ;; ScienceDirect ELSEVIER journa l ho m e pa ge: www ./ loc ate/chnjc Article Effects of alkaline additives on the formation oflactic acid in sorbitol hydrogenolysis over NijC catalyst }unjie Zhang响， Fang Lu a,#, Weiqiang Yt户I Rui Lu a川ie XU a,* •StQte Key LaboraωryofCaω加is， Dalian Insti阳te ofChemical Physics, ChineseAcademy ofSciences, Dalian National Laboraωryfor Clean Energy, Dalian 116023, Liaoning, China b University ofChineseAcademy ofSciences, 8eijing 100049, China ARTICLE INFO ABSTRACT Ar忧lehisωry: Lactic acid is produced as a m句。r byproduct during sorbitol hydrogenolysis under alkaline condi- Received 28 Au职1St 2015 tions. We investigated the effects oftwo dífferent alkalíne additives, Ca(OH)z and La(OH)3,on lactic Accepted 24 5eptember 2015 acid formation during sorbitol hydrogenolysis over Ni/Cωtalyst ln the case of Ca(OH)2, the selec- Publíshed 51anuary 2016 刷ty of lactic acid was 8.9%. In con阳st， the inclusion of La(OH)3 resulted in a sorbiω1 conversion of 99% with only tr百ce quantities of lactic acid being detected. In addition, the total selectivity to- wards 由e C2 and C4 products increased from 20.0% ω24.5% going 仕om Ca(OH)2 to La(O町3. Keywo叫s: Lactic acid ηlese results therefore indicated that La(OH)3 could be used as an efficient aJkalíne additive to