PPY掺杂离子对电催化脱氯PdPPYNi电极的影响.pdfVIP

Vol. 45 No.6 第45 卷第6 期 哈尔滨工业大学学报 June 2013 2013 年6 月 JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY PPY 掺杂离子对电催化脱氯Pd/PPY/Ni电极的影晌 李君敬，刘惠玲，程修文，陈清华，王执伟 (哈尔滨工业大学市政环境工程学院，城市水资源与水环境国家重点实验室，15(朋O 哈尔槟) 摘 要:为制备高效稳定的用于电催化去除氯代有机物的电极，采用扫描电子显微镜和电催化脱氯实验考察不同聚咣 咯掺杂离子对 PdlPPY/Ni 复合电极的形貌和电催化加氢脱氯性能的影响.将制备的电极在强吸附性阴离子存在情况 下，考察其电催化性能的变化.结果表明，掺杂离子对复合电极的形貌和电催化性能有显著的影响，对甲苯磺酸掺杂的聚 咣咯对应的 PdlPPY(PTS/Ni 电极有最高的电催化加氢脱氯效率(高达91. 1%) ，高氯酸纳掺杂的聚咣咯对应的电极电催 化性能最差.电催化体系中强吸附离子(CI0 - , Cl- )的存在对电极性能有微弱影响，表明电极具有良好的稳定性，可高 4 效去除水中的氯盼类氯代有机物. 关键词:电催化加氢脱氯;掺杂离子;形貌;脱氯性能;强吸附离子 中固分类号: X703.1 文献标志码:A 文章编号: 0367 -6234(2013)06-∞48 -05 Effects of dopaot ions of polypyrrole 00 Pd/PPY/Ni composite electrode for electrocatalytic hydrodechlorioatioo U Junjing , UU Huiling , CHENG Xiuwen , CHEN Qinghl蝠， WANG Zhiwei (State Key Laboratory of Urban Water Resource and Environrnent , Sch∞，1 of Municipal and Environmental Engineering , Harbin Institute of Technology , 15∞90 Harbin , China) Abstract: Electrocatalytic hydrodechlorination (ECH) is an efficient method for dechlorination of chlorinated organic pollutants. Preparation of working electrode used in ECH is of great importance. Dopant ions doped in polypyrrole had effects on PdlPPY/Ni composite electrode. The influences of dopant ions on morphology and ECH performance of composite electrode were investigated. The removal rates of 2 ,4 - DCP for PdlPPY(PTS)1 Ni electrode reached 9 1. 1% , higher than others , especially than 由at of PdlPPY ( NaCI04 ) INi. The effects of strongly adsorbed anions (CI04 - , Cl-) in catholyte on elect