多孔磷酸铁锂薄膜的制备与表征.pdfVIP

• 34 • 材料导报B:研究篇 2014 年 5 月(下〉第 28 卷第 5 期 多孔磷酸铁锤薄膜的制备与表征铃 展飞，戴金辉， 吴平伟，刘 青，刘文栋，徐玉磊 (中国海洋大学材料科学与工程研究院， 青岛 266100) 摘要 采用溶放-凝胶技术与 PS 微球模板相结合，在铭基板上成功常j 备了亚微米连续给窝网状 LiFePO. 薄 膜。采用 XRD、SEM 等测试手段对薄膜的组成及显微形貌进行了农征，研究了成蹊工艺、涂膜方法及模板然直径等 因素对薄膜形貌的影响规律，并对薄膜形成机埋进行了初步探讨。结果表明，成E莫过程中模板表面溶肢层与模板之 间的作用力是影响薄膜结构的关键因素;对于600 run PS 冻模板和200 nmPS球模板获得完好LiFePO. 薄膜的最佳 方法分别为浸渍提拉法和旋涂法。 关键词 溶胶，凝胶 LiFePO. PS球模板薄膜 cp图分类号:TQ150 文献标识码:A Synthesis and Characterization of LiFeP04 Porous Thin Film ZHAN Fei , DAI ] inhui , WU Pingwei , LIU Qing , LIU Wendong , XU Yulei Onstitute of Materials Science and Engineering , Ocean University of China , Qingdao 266100) Abstract By the application of sol-gel technology combined with PS microsphere templates , continuous submi- cron honeycomb LiFePO. film were prepared on the aluminum substrate. The combination of the film and its micro- structure were characterized through different approaches , such as XRD , SEM and 50 on. Then the effect of film forming techniques , painting film method and the sphere diameter of template on the morphology of films was studied. Meanwhile , the formation mechanism of the film was also discussed preliminarily. It comes to the conclusion that du- ring the process of film forming , the interaction force between the sollayer surface of template and the template 响11 have a crucial effect 10 the film structure; as 10 the 600 nm PS template as a sphere and the 200 run PS, the best ap- proach to achieve a perfect LiFePO. film is through dipping-coating method and spin-coating method. Keywω吐s sol-gel , L iFePO. , PS template , thin film 近年来，随着煤炭、石汹资源的极度开采，人们对能源危