多钒取代磷钼杂多酸的合成及表征.pdfVIP

Vol. 36 No.l 高师理科学刊 第 36 卷第1 期 2016 年 1 月 Joumal of Science ofTeachers College and University Jan. 2016 文章编号: 1 ∞7-9831 (2016) 01-∞52-04 多饥取代磷铝杂多酸的合成及表征 尹彦冰，裴笠舟，王会淤 (齐齐哈尔大学化学与化学工程学院，黑龙江齐齐哈尔 161∞6 ) 摘要:采用分步加酸、乙酷革取的方法，合成了 4 种 Keggin 及 Dawson 型多机取代磷细杂多酸.利 用Ff-IR 、 XRD 和 TG 对杂多酸进行表征，证明所得杂多酸的组成分别为 H PMo7V O咽. 8H 0 (标 2 8 S 记为 K-V5) , H PMo V 0咄. 13H 0 (标记为 K-V ) , H\l P Mo V 062 26H 0 (标记为 D-V )和 13 2 5 9 6 6 2 6 2 5 H12P Mo12V6062 • 20H 0 (斗示4己为 D-V6) . 2 2 关键词:多在凡取代磷钮杂多酸;合成;表征 中图分类号: 062 1.3 文献标识码: A doi: 1O.3969/j.Ìssn.l 007-983 1.2016.0 1.013 Synthesis and characterization of polyoxovanadium substituted heteropolyacid YIN Yan-bing , PEI Li-zhou , WANG Hui-song ( School of Chemistry and Chemical Engineering , Q叩har University , Qiqihar 161∞6 ， China) Ahstract: Four Keggin type and Dawson type polyoxovanadium heteropoly acid were synthesized by the method of adding acid gradually and extracted by ethyl ether. The structures of heteropoly acid were confirmed by IR , XRD , 飞 TG. Structures were shown as following: H PMo T5040 • 8H 0 (marked K-Vs) , H PMo6V Ü40 13H 0 (marked 8 7