多孔阳极氧化铝模板组装Fe纳米线及其表征.pdfVIP

Chinese J. Chem. Eng. , 12 (2) 315 - 318 (2004) RESEARCH NOTES Preparation and Characterization of Fe N anowire Arrays Embedded in Porous Anodic Aluminum Oxide Templates* CHI Guangjun(迟广俄) and YAO Suwei(挑素薇)忡 School of Chemical 巴ngineering and Technology, Tianjin University，丁[，ianjin 300072 , China Abstract Fe nanowire a.rrays are prepared by electrodeposition in porous anodic aluminum oxide template from a composite electrolyte solution. These nanowires have a.n uniform dia.meter of approximate 25 nm and a length in e且cess of 2.5μm. The micrographs a.nd crystal structure鸣。f Fe na.nowires are studied by transmission electron microscopy (丁EM)， selected-a.rea electron diffract.ion (SAED) , and X-ray diffraction(XRD). It is found that each nanowire is essentia.lly a. single crystal and has a di仔erent orientation in ea.ch array. Hysteresis loops of Fe nanowire array show that its e剧y magnetiza.tion direction is perpendicular to the sample plane. Keywords electrodeposition, nanostructure , aluminum anodization 1 INTRODUCTION posìted in nanoporous AAM by a novel deposìtion pro- In the last a few years , the fabrication of nanowire cess. The technique is used to fabrìcate single crystal arrays has attracted considerable interest , due to not Fe nanowire arrays with cost-effectiveness and simplic- only the fundamental interest in these material日 but ìty ìn operation. The structur骨 and magnetic proper- also the potential application of their properties[l]. ties are characterìzed. In particular , the preparation of magnetic metal 2 EXPERIMENTAL nanowire a