季铵型阳离子淀粉的制备及表征.pdfVIP

化学工程师 Sum 147 No. 12 Chemical Engipeer 2007 年 12 月 文章编号:1002-1124(2∞7)12 -∞11 -04 发 开 与 研 科 季铁型阳离子淀粉的制备及表征 王 玲，周朝昕，吴 RR {中国地质大学材料科学与化学工程学院，湖北武汉 43∞74 ) 摘 要:本文选用半干法工艺制备季镀型阳离子淀粉，具体试验了季镀型阳离子酷化剂 N - (2 ， 3 环 氧丙基)三甲钱盐酸盐(GTA) 及季镀型阳离子淀粉的制备方法，对影响 GTA 1!itJ 备及季镀型阳离子淀粉制 备的主要因素:原料的配比、pH 值、反应时间及反应温度进行了研究。通过使用实验室配制的模拟废水检 测季钱型阳离子淀粉的絮凝效果，得出制备阳离子酷化剂和制备阳离子淀粉的最优化条件。应用红外光 谱对产品结构进行分析表征，证明了淀粉的阳离子化。 关键词:阳离子淀粉;阳离子酷化剂;制备;表征 中图分类号:0636.1 文献标识码:A Preparation and token of quaternary ammonium type cationic starch WANG Li吨， ZHOU Chao - xin , WU Li (Dept. of Material Science Cheπ， ical Engineering , China Univ. of Geosciences , Wuhan 430074 , China) Abstract :We selected the semi - dry process as the technologic method to prepare quatem缸γammonium type cationic starch. In this thesis , the method of preparation of cationic starch and etherifying agent (GTA) was studied. The experiments also studied the main influence factors about it. The ratio of the components 、 pH value 、 time and temperature. By testing the flocculation effect of quatemary ammonium type cationic starch on analog wastewater , we set up the optimum synthesis condition of GTA and quatemary ammonium type cationic starch. Study the product by IR to confirm starch cationization. Key words: cationic starch; cationic etherifying agent; preparation ;token 的矛盾[4] 。阳离子型改性淀粉包括季镀型、叔胶 阳鸭子淀粉是天然淀粉经物理化学等方法处 理后，改变了淀粉分子中的 D- 毗喃葡萄糖单元的/