不同溶剂对准东煤钠脱除及特性的影响.pdfVIP

第 22 卷 第 5 期 燃 烧 科 学 与 技 术 Vol.22 No.5 2016 年 10 月 Journal of Combustion Science and Technology Oct. 2016 DOI 10.11715/rskxjs.R201603022 不同溶剂对准东煤钠脱除及特性的影响 孙琪琪，乔 瑜，杨怀舟，刘 帅，徐明厚 (华中科技大学煤燃烧国家重点实验室，武汉 430074) 摘 要 ：针对目前的研究热点准东煤，选取水、2 种有机酸及 3 种无机酸，对准东煤进行浸洗．研究不同溶剂对碱 金属脱除及其他特性的影响．结果表明，无机酸在脱钠方面效果较好，但也会造成有机质破坏等影响，而柠檬酸对 于孔隙增大起到关键作用，醋酸对于碱金属脱除效果较好，表面破坏小，可提高准东煤的热解性能．水洗则影响 最弱． 关键词 ：准东煤；去离子水；无机酸；有机酸 中图分类号：TK16 文献标志码 ：A 文章编号 ：1006-8740 (2016)05-0441-05 Effects of Different Solvents on Sodium Removal and Other Characteristics of Zhundong Coal Sun Qiqi ，Qiao Yu ，Yang Huaizhou ，Liu Shuai ，Xu Minghou (State Key Laboratory of Coal Combustion ，Huazhong University of Science and Technology ，Wuhan 430074 ，China) Abstract ：In this research ，deionized water ，two kinds of inorganic acids and three kinds of organic acids were chozen to wash Zhundong coal ，which is a hot area of research today．Alkali metal removal and the effects on other characteristics were studied in the research．The results show that inorganic acids have better effect on sodium removal ，but they will cause damage to organic matter．Citric acids play a key role in increasing the pore size．Acetic acid is better at removing alkali metals ，which can improve the pyrolysis performance of Zhundong coal ，with little damage to the coal surface．The effect of water is the weakest. Keywords ：Zhundong coal ；deionized water ；inorganic acid ；organic aci