碳纳米管–聚吡咯复合材料在超电容器中的应用-宁波市化工数字图书馆.PDFVIP

第12 期 电 子 元 件 与 材 料 Vol.21 No.12 2002 年12 月 ELECTRONIC COMPONENTS MATERIALS D e c . 2002 研究与试制 R D 碳纳米管–聚吡咯复合材料在超电容器中的应用 1 1,2 3 3 漆海波 周 啸 姜翠玲 楚红军 1.清华大学化工系 北京 1000842.清华大学材料科学与工程研究院 北京 1000843.湖南湘怡中元科技股份 有限公司 湖南 株洲 412008 摘要:在碳纳米管 CNT 基体上用化学聚合或电化学聚合方法沉积聚吡咯 PPy 制得复合材料 再以此类复 合材料为活性物质制作电极 组装成原型超电容器 并对其进行了循环伏安 恒电流充放电等电化学测试 用此类复 合材料制成的原型超电容器的比容量 23.6 F/g 与纯碳纳米管 2.3 F/g 或纯聚吡咯 3.9 F/g 制成的原型电容器比 较 发现复合电极电容器比容量的提高不是简单的加和效应 而是协同效应所致 关键词:碳纳米管 聚吡咯 超电容器 循环伏安 法拉弟赝电容 中图分类号: TM53 文献标识码:A 文章编号:1001-2028 2002 12-0029-04 The Application of Carbon Nanotube-polypyrrole Composite to Supercapacitor 1 1, 2 3 3 QI Hai-bo , ZHOU Xiao , JIANG Cui-ling , CHU Hong-jun (1. Department of Chemical Engineering, Tsinghua University, Beijing 100084; 2. School of Material Science and Engineering, Tsinghua University, Beijing 100084; 3. Hunan Xianyi Zhong Yuan Science and Technology Limited Company, Zhuzhou, Hunan 412008) Abstract: Carbon nanotube-polypyrrole composite was prepared by polymerizing polypyrrole onto carbon nanotubes with chemical or electrochemical methods. With the acquired composites as active materials of electrodes, the prototype supercapacitors were made. Electrochemical tests, such as cyclic voltammetry, charging-discharging cycles were carried out. The specific capacitance the capacitor with composite electrodes has been greatly enhanced (up to 23.6 F/g) compared with the that of those capacitors with pure carbon nanotube electrodes (up to 2.3 F/g) or pure