锂电池材料的合成方法.pptVIP

LiCl和KCl混合溶剂的熔点随KCl和LiCl不同摩尔比时的变化关系： LiCl和KCl混合溶剂的熔点随不同摩尔比时的变化关系 D. S. Coleman and P. D. A. Lacy， Mat. Res. Bull. Vol. 2, pp. 935-938, 1967 7.微波法 (Microwave Synthesis) 微波加热是介质材料自身损耗电场能量而发热的一种加热方式，具有加热速度快、加热均匀、节能高效、易于控制、低温杀菌、选择性加热、安全无害等特点 。微波加热法制备无机纳米材料与传统的加热方法相比具有明显的优势，是一种较实际且高效率的制备技术 。 Gang Yang et al., J. Phys. Chem. B 2005, 109, 11186-11196 The modified microwave reaction system was designed on the basis of a domestic microwave oven (National MN-MX26WF, frequency 2.45 GHz, maximum power 800 W, multimode oven).18a The temperature of the reaction system during irradiation was monitored online by using a sheathed Pt-Rh thermocouple connected with a computer. A 42 g sample of graphite powder (30 mm) was used as the secondary heater, sealed in a 50 mL alumina vessel. The vessel was placed inside the wellinsulated cavity with Kaowool. The alumina crucible loaded with 3 g of reactants was placed in the center of the secondary heater. A mode stirrer (a reflective and fan-shaped paddle) was used to ensure that the average field experienced by the sample was approximately the same in all directions.18b In the upper part of the crucible, there was a vent hole to air to ensure that the expected oxidation of vanadium in LiV3O8 could be obtained. The starting materials LiOHaH2O and V2O5 were mixed in a stoichiometric ratio, and then irradiated at different irradiation time and power (L: the lowest power, ML: the middle lower power, M: the middle power, MH: the middle higher power, and H: the highest power), and finally allowed to cool in the microwave cavity. All the reagents were analytical grade without any pretreatment. The relevant experimental details are listed in Table 1. For comparison, LiV3O8 was also prepared by traditional solid-state reaction with use of an electric furnace according to the literature.11 The stoichiometric mixture of LiOHaH2O and V2O5 was heated at 650 °C for 10 h, and the obtained sample was termed CP650. V. Subramanian, C. L. Chen, H.