现代仪器分析第二版课后答案(国外英文资料).doc

现代仪器分析第二版课后答案(国外英文资料) f8d Modern instrument analysis problem solving problem solved 2009 spring Chapter 12 potential analysis and ion selective electrode analysis P216 What is a potential analysis? What is ion selective electrode analysis? Answer: the use of electrode potential and certain ions in the solution of the relationship between the activity or concentration to measure physical activity under test or concentration of electrochemical analysis called potential analysis. The potentiometric analysis of the electrode with ion selective electrode is called ion selective electrode analysis. What is the indication electrode and reference electrode in the analysis of potential? What is the difference between a metal electrode and a membrane electrode? The answer: the electrochemical potential with ion activity under test or concentration in the solution change and change, and can reflect the concentration of ion activity under test or electrode as indicator electrode. Electrode potential is constant, and the electrode that is not affected by the composition of the solution or the flow of current is called the reference electrode. The sensitive membrane of a metal base electrode is made from a rigid matrix glass fused by an ion exchange. Membrane electrode of sensitive membrane is commonly by the solubility in water is small, and conductive refractory metal salt by pressure or control of monocrystalline, polycrystalline or mixed crystal active film. What is TISAB solution? What does it do? A: in the determination of solution to join a lot of, to determine the inert electrolyte ions on interference and moderate pH buffering agent and masking agent, constitute the total ionic strength regulating buffer (TISAB). The effect is: constant ion intensity, control solution pH, elimination of interference ion influence, stable fluid potential. 5. 25 ℃, with pH = 4.00 standard buffer solution measured battery: glass electrode | H + (a = X mol? L - 1) ║ saturated calomel electro