碳纳米管电极原位产生过氧化氢及对亚甲基蓝脱色效果研究.docVIP

碳纳米管电极原位产生过氧化氢及 李文军1，戴启洲2，胡翔1*，邵磊1 （北京化工大学 化学工程学院，北京 100029） 摘要：将多孔疏水性薄膜66.17 mg/L，探讨了过氧化氢原位产生的机理。在此基础上考察了原位过氧化氢氧化工艺下对亚甲基蓝的脱色效果，并分析了其脱色机理。 关键词：碳纳米管活性电极 中图分类号： 文献标识码：A 文章编号： generating hydrogen peroxide by carbon nanotubes electrode and application in decolorization of wastewater containing methylene blue Li Wenjun1， Dai Qizhou2， Hu Xiang1， (1College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China 2College of Biological Environmental Engineering, Zhejiang University of Technology, Zhejiang 300014, China ) Abstract: Carbon nanotubes was immobilized into porous hydrophobic conductive thin film to construct the electrochemical cathodic reduction system construction, so as to realize the in-situ generated hydrogen peroxide in cathode. The studies of electrodes characteristics have shown that the electrode has good activity in a wide voltage range. The effects of cathode potential, electrode composition, and oxygen flow rate and electrolyte concentration on the production of in situ generated hydrogen peroxide were evaluated The concentration of hydrogen peroxide is up to 66.17 mg/L when the reaction time is 120 min under the optimized conditions. The mechanism of in situ generated hydrogen peroxide was also investigated. On this basis, the effectiveness of in-site hydrogen peroxide oxidation process in the decolorization of wastewater containing methylene blue was evaluated, and the decolorization mechanism was analyzed. Keywords：arbon nanotubes; hydrogen peroxide; active electrode; methylene blue 我国是全球第一大生产、消费和贸易大国，行业产生的废水具有高浓度、高盐、难降解等特点，是水处理领域长期研究的重点和难点。电化学氧化技术近年来已成为研究的热点[1-6]。[7-9]。 碳纳米管自从问世以来由于其卓越的催化等性能引起材料、环境等领域研究者的广泛关注[10-13]。传统的碳纳米管研究主要集中在材料本身的特性研究，近年来，有研究者尝试将其固定化于 (二氧化钛等催化剂上并用于环境水处理领域，拓展了碳纳米管的研究领域[14-16]。 基于上述两方面的本文将碳纳米管固定化，利用碳纳米管的催化活性，在电化学体系原位过氧化氢，并在优化条件下处理盐废水。其主要特点为在温和的电化学体系下，控制阴极电位，利用阴极产生的过氧化氢降解。 1 实验部分 1.1 实验药品 碳纳米管Purity95 %，Diameter 20 nm -40 nm，Length 5 (m -15 (m，深圳纳米港有限公司石墨粉光谱纯聚四氟乙烯乳液PTFEFR