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Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics This journal is © The Owner Societies 2011 Actinide sulfides in the gas phase: Experimental and theoretical studies of the thermochemistry of AnS (An = Ac, Th, Pa, U, Np, Pu, Am and Cm) Cláudia C. L. Pereira,a b a c Colin J. Marsden,* Joaquim Marçalo* and John K. Gibson a Unidade de Ciências Químicas e Radiofarmacêuticas, Instituto Tecnológico e Nuclear, 2686-953 Sacavém, Portugal b Laboratoire de Chimie et Physique Quantiques, UMR 5626, IRSAMC, Université Paul Sabatier, 31062 Toulouse Cedex 9, France c Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA Supplementary information Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics This journal is © The Owner Societies 2011 + a Table S1 Reaction products and kinetics for the reactions of AnS with 1,3-butadiene and isoprene Reactant ion C H k/k [k] C H k/k [k] 4 6 COL 5 8 COL ThS+ ThSC H + (45) 0.40 [0.41] ThSC H + (15) 0.43 [0.45] 2 2 2 2 ThSC H + (40) ThSC H + (30)