新颖含磷难燃剂之合成与监定及其环氧固化物之物性研究(论文摘要).docVIP

中文摘要 本實驗使用N-(4-hydroxyphenyl)maleimide (HPM )合成兩種馬來醯亞胺單體Epoxy-Maleimide Monomer (EMM)、Benzoxazine-Maleimide monomer (BMM)經由FTIR和NMR(1H)作結構鑑定。將上列之馬來醯亞胺單體添加不同比例DOPO以DSC探討交聯行為，並利用TGA、DMA、UL-94V、DEA等儀器測量共聚物之物性。? ? 利用DSC計算共反應的硬化動力學參數，結果顯示推電子基效應和立體障礙為影響反應的主要因素；在物性上測試，雖然導入DOPO使的Tg下降，但是在電氣性質和熱穩定性質上有顯著的提升；在UL-94V難燃測試中，在氮-磷共乘效益下， DOPO的添加量在EMM/DOPO系統只須添加到15phr；BMM/DOPO系統只須添加到5phr，即可達到V-0等及，有效改善樹脂的難燃性質。In this study, two kinds of Epoxy-Maleimide Monomer (EMM) and Benzoxazine-Maleimide monomer (BMM) were synthesized from N-(4-hydroxyphenyl)maleimide (HPM ). The monomer EMM or BMM was cured with DOPO at various content, and their curing behaviors investigated by differential scanning calorimetry (DSC). The properties of the resins were studied by Dynamic viscoelastic analysis (DMA), Thermogravimetric analyzer (TGA), Dielectric analyzer (DEA) andUL-94V test.The kinetic parameters were studied by dynamic DSC. According to the results, the most main factors to influence reaction are electric transform and steric hindrance. The physical poperties measurement, although introduced DOPO into EMM and BMM which reduced the crosslinking density of these resins and Tg of the cured resins decreased as the DOPO content increased, however the co-reactant resins exhibited better themal stability and lower dielectric constant. In UL-94V test, indicated that because of the synergistic effect, the UL-94 V-0 rating can be achieved withphosphorus content of as low as 5~15 phr. 總目錄 中文摘要---------------------------------------------------------------------i英文摘要---------------------------------------------------------------------ii致謝---------------------------------------------------------------------iii目錄---------------------------------------------------------------------iv表目錄---------------------------------------------------------------------viiScheme---------------------------------------------------------------------ix圖目錄-------------------------------------------------------------------