碳纳米导静电涂膜的分散及耐油老化性能研究.PDF

28 5 武 汉 理 工 大 学 学 报 Vol. 28 No. 5 2006 5 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY May 2006 1,2 1 3 赵福君 , 巴恒静 , 潘 雨 (1., 150006;2., 163712; 3. , 100044) : 多壁碳纳米管由于很难分散为独立颗粒, 因此作为涂料使用受到了一定的限 , 而这些碳纳米管的许多潜在 应用,如在极低的浓度下获得导电性,都与它的比表面积密切相关因此碳纳米管分散性的好坏对其性能有决定性的影 响提出了一种既能提高分散性, 又不破坏碳纳米管原有性能的方法, 这种方法能够去除碳纳米管团块中的硅藻土等矿 物,加入分散剂后形成稳定的胶体还对碳纳米管导电涂层的耐油老化性能进行了分析研究, 发现不同表面处理工艺对 油在碳纳米管涂层的扩散系数影响很大, 喷砂处理较打磨处理耐油性增加 20% 左右另外还分析了涂料的固化条件及 老化条件对涂层耐油性的影响 : 碳纳米管; 导电涂料; 分散; 耐久性 : TB 304;TE 821 : A : 167124431(2006)052 00172 04 Film Durability of Carbon Nanotub Conductiv Coatings Und r Oil Attack 1, 2 1 3 ZH AO F u2j un , BA H eng2j ing , P AN Yu (1.Depart ent ofCivil Engineering, Harbin Instituteof Technology, Harbin 150006, China;2. Engineering Design Instituteof Daqing Oilfield Construction Group,Daqing 163712, China; 3. School ofCivil Engineering Architecture, Beijing Jiaotong University, Beijing 100044, China) Abstract: Theuseof ult2i walled carbon nanotubes for coatings applicationshasbeen quiteli ited becauseofproble s asso2 ciated with obtaining dispersions of individual tubes. The potential for uniqueproperties associated with these aterials, such as obtaining electrical conductivity at very low volu e concentrations, is dependent upon exploiting their very large geo etric as2 pect ratios. Therefore, dispersion quality has a direct relationship to perfor ance. We have developed a novel dispersion tech2 nique that appears to yield high quality dispersions without significant da ag