亲水性聚合物多孔载体制备及其三相流化床生物挂膜特性研究.pdfVIP

第29卷第4期 Vo1．29 No．4 2007年 12月 Dec．20o7 Study on Synthesis of a Hydrophilic Porous Carrier and its Properties f0r Biofilm Formation in Three—phase Fluidized Bed Reactor WEIChao—hai‘。 LILei。 DENGZhi—yi。 WUXiao一／ (College of Environmental Science and Engineering．South China University of Technology．Guangzhou 510640 China) I Abstract】 The current carriers for bi~lm formation in three—phase fluidized bed reactor have some disadvan— tage such as high density，smooth surface and hydrophobicity etc．A new style hydrophilic porous(GPUC)carri— 相 Naers addition of uc0se and absorbent—power activated carbon was prepared by foaming method．The effects of monomer composition，catalyses and foaming agent on the structure character of the GPUC carriers were studied． 大-詈 潭 S The structure of GPUC carriers Was characterized by BET，IR spectra and thermal analysis(TG)and the mecha— nism Was further explored．Four kinds of contrast test were made using the GPUC carriers，the neat porous carri— 学 ers，granular activity c~bon(GAC)and polypropylene particles for forming biofilm in three—phase fluidized bed reactor to study the effect of carrier surface physicochemical property on biofilm and bioactivity．Th e results showed 自 m a that the optimized composition was made of polyether tfiol of 50 g，toluene diisocyanate of 20 g， ucose of 7 g， 然 X PAC of6 g，stannous octanoate of0．2 g，tfiethylene diamine of0．4 g，water of1．5 g．Under the conditions，the ． 科 g抓 porosity and water absorption of GPUC carriers were 91．7％ and 315．2％ 。respectively．The biomass and bioac— a 学 tivity attached on the GPUC carriers were 4．65 gVSS／L and 103 mg O2