回收WC制备硬质合金过程中的碳量控制.pdfVIP

第l2卷第6期 粉末冶金材料科学与工程 2007年l2月 、，01．12 NO．6 Materials Science and Engineering of Powder Metallurgy Dec．2007 回收WC制备硬质合金过程中的碳量控制 赵万军，阮建明，杨海林，谢健全 (中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：通过化学成分分析和扫描电镜研究锌熔法回收的WC与钨粉碳化后的原生WC粉在化学成分、颗粒形貌 和费氏粒度等方面的不同。以锌熔法回收的WC粉和Co粉为原料，经过调碳，制备不同含碳量的YG8混合料， 再经相同的压制、真空烧结制度制得 YG8合金，研究碳含量对该合金组织及力学性能的影响，并重点探讨在真 空烧结过程中的控碳问题。研究表明，对回收碳化钨进行适当的碳量调配，并通过工艺控制，可以生产出综合性 能良好的硬质合金制品。 关键词：硬质合金：回收WC：真空烧结；碳量控制 中图分类号：TF 125．241 文献标识码：A 文章编号：1673—0224(2007)6—359—05 Carbon content control during producing cemented carbide with recovered WC ZHAO Wan-jun，RUAN Jian—ming，YANG Hai—lin，XIE Jian—quan (State Key Laboratory ofPowder Metallurgy，Central South University,Changsha 410083，China) Abstract：The differences on chemical composition，morphology and hardness between zinc melting WC powder and original WC powder were studied through chemical composition analysis and scanning electron microscopy．Using WC powder and Co powder recovered by zinc process as raw materials，six groups of WC一8Co mixtures were prepared through carbon amount adjustment．Then，with the same pressing and vacuum sintering method，YG8 alloys were fabricated from these mixtures，and the influence of carbon content on the microstructure and mechanical properties was researched．Finally，the problem of controlling carbon content was discussed．The results show that cemented carbide with fine comprehensive properties can be produced by using recoverad WC through carbon controlling technology． Key words：cemented carbide；recovered WC；vacuum sintering；carbon content control 自从硬质合金问世以来，其回收利用问题就一直 通常是将废合金在高温下(一般为900～1 000℃1与锌 为业内人士所关注【l ]。近年来，许多国家把硬质合金