铀(VI)和磷酸三丁酯配合物在离子液体中的电化学行为研究.PDFVIP

第28卷第2期 南华大学学报(自然科学版) Vol郾28 No郾2 2014年6月 Journal of University of South China(Science and Technology) Jun郾2014 文章编号:1673-0062(2014)02-0099-04 铀(VI)和磷酸三丁酯配合物在离子液体中 的电化学行为研究 邱凌云,刘良军* (南华大学 核科学技术学院,湖南 衡阳421001) 摘摇 要:选择磷酸三丁酯(TBP)作为配体,考察铀酰—TBP 配合物在1鄄丁基鄄3鄄甲基咪 唑双三氟甲基磺酰亚胺盐([Bmim][NTf ])离子液体的萃取及电化学行为.发现铀 2 (VI)经过两步单电子还原为铀(IV),且铀(V)至铀(IV)的还原电位(-2.7 V Vs. Pt)超过此体系的电化学窗口,电沉积物为U (PO ) ,继续热处理电沉积产物约 3 3 4 573 K时转化为UP O .此研究表明离子液体可能在乏燃料金属的电化学分离中表现 2 7 出乐观的前景. 关键词:铀;离子液体;萃取;电化学还原 中图分类号:TU212摇 摇 摇 文献标识码:B Electrochemistry Behavior Research of Uranium and TBP爷s Coordination Compoundin Ionic Liquids QIU Ling鄄yun,LIU Liang鄄jun* (School of Nuclear Science and Technology,University of South China,Hengyang,Hunan421001,China) Abstract:Herein,TBPisselectedasaligandtoinvestigatetheextractionandelectrochem鄄 ical behavior,which is coordination compound of uranyl鄄TBP and [Bmim][NTf ] system 2 in our work.It isfound that hexavalent uranium transformsinto tetravalent uranium by two stepsof singleelectronreduction.Andthereductionpotential,pentavelenturaniumtotetra鄄 valent uranium,exceeds the system爷s electrochemical window.The electrodeposition is U3 (PO ) ,then turnsto UP O by heating at about573 K.It indicatesthat ionicliquidsmay 3 4 2 7 show bright prospect in electrochemical separation of spent nuclear fuel reprocessing. key words:uranium;ionic