规整填料塔精馏的Marangoni效应.PDFVIP

第 53 卷 　第 6 期 化 　　　工 　　　学 　　　报 Vol . 53 　№6 ( ) 2002 年 6 月 Journal 　of 　Chemical 　Indust ry 　and 　Engineering 　 China J une 　2002 研究论文 规整填料塔精馏的Marangoni 效应 　　　 耿 　皎　　洪 　梅 　　肖　剑 　　张志炳 　　　　　 (南京大学化工系 ,江苏 南京 2 10093) 　　　　　 摘 　要 　选用 6 种代表性物系对陶瓷板波纹和不锈钢丝网规整填料进行全回流精馏实验 ,考察 Maran goni 效应对 规整填料液体流动分布及传质的影响. 结果表明:对纯有机体系 ,Marangoni 效应影响较小 ;而对有机物的水溶液 , Marangoni 效应严重影响着填料的润湿和传质效率. 关键词 　规整填料 　表面张力 　Marangoni 效应 　传质 中图分类号 　TQ 02 1. 4 　 　 　 　 　文献标识码 　A 　 　 　 　 　文章编号 　0438 - 1157 (2002) 06 - 0600 - 07 MA RA NGONI EFFECT IN D ISTILLATION WITH STRUCTURED PACKING GENG Jiao , HONG Mei , XIAO Jian and ZHANG Zhibing ( ) Dep art ment of Chem ical Eng ineering , N angj ing University , N anj ing 2 10093 , J iangs u , China Abstract 　To investigate t he influence of Marangoni effect on liquid flow and it s dist ribution as well as sep aration efficiency of st ruct ured p acking , binary distillation experiment s were carried out at tot al reflux using six t ypical systems for ceramic corrugated sheet and st ainless steel gauze st ruct ured p acking . It was shown t hat t he influence of Marangoni effect was small for p ure organic systems. However ,for aqueous organic systems , hydraulics and mass t ransfer of st ruct ured p acking were bot h st rongly influenced by Marangoni effect . Key words 　st ruct ured p acking ,surface tension ,Marangoni effect ,mass t ransfer 量增加 ,轻组分含量减少 ,则塔内液体形成正的表面 引　言 张力梯度