硫系玻璃微结构缺陷对其二阶非线性光学性能的影响-中国有色金属学报.PDF

18 7 2008 7 Vol.18 No.7 The Chinese Journal of Nonferrous Metals Jul. 2008 1004-0609(2008)07-1299-06 1, 2 1, 2 2 3 (1. 411105 2. 411105 3. 430070) GeSbS Sb2S3 GeSbSSb S 2 3 O 437 A Effects of chalcogenide glass microstructure defects on its second order nonlinearity 1, 2 1, 2 2 3 GONG Yue-qiu , LIU Si-wei , LI Xu-jun , ZHAO Xiu-jian (1. Faculty of Materials Optoelectronics and Physics, Xiangtan University, Xiangtan 411105, China; 2. Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Xiangtan University, Xiangtan 411105, China; 3. Key Laboratory of Silicate Materials Science and Engineering, Ministry of Education, Wuhan University of Technology, Wuhan 430070, China) Abstract: GeSbS chalcogenide glasses with various ratios of germanium and antimony were prepared by conventional melt-quenching method. The results of Raman, SEM and EPMA tests show that the microstructure defects of the chalcogenide glasses play an important part in their second-order nonlinear optical properties (SNOP). The glasses show large SNOP because of Sb S microcrystal or the mental antimony in the glasses even before they were polarized. After 2 3 the electrical/thermal polarized, GeSbS glasses show larger SNOP with the increase and growth of the microcrys