生物模板法制备微纳米二氧化锡.pdfVIP

Vo l. 40 N口.5 第 40 卷第 5 期 化工新型材料 2012 年 5 月 NEW CHEMICAL MATERlALS • 151 • 生物模板法制备微纳米二氧化锡 何琴l 黄保军2 李颖颖1 法文君2 (1.许昌学院化学化工学院，许昌 461000;2. 许昌学院表面微纳米材料研究所，许昌 461000) 摘要 以 snCl， • 5日， 0 为起始原料，采用不同的生物模板(定量滤纸、鸡蛋内蹊).通过浸i责和燃烧.在常压空气气 氛中成功地制备出具有不同生物形态的微纳米 Sn句。采用 X 射线衍射仪(XRÐ)和扫描电子显微镜(SEM)表征样品的 相组成和微观结构。结果表明z 两种模板所带l 得的产物纯度很高，且很好地复制了原模板的形貌。同时，研究了制备条件 绪如般烧温度和反应物浓度付产物结构、形貌和尺度的影响，并初步探讨了不同生物形态的微纳米SnÜz形成的机理。 关键词 生物模板，二氧化锡，定量滤纸，鸡蛋内膜 Biosynthesis of Sn02 with micro/nano structure from biological templates He Qín1 Huang Baojun2 Li Yingying 1 Fa Wenjun2 (1. College of Chemistry and Chemícal Engineering , Xuchang University , Xuchang , 461000; 2. Institute of Surface Micro and Nano Materials.Xuchang University ,Xuchang 461000) Abstract Biomorphic SnÜz with micro-and nanostructures was successfulIy prepared from different biotemplat西 such as filter paper and egg shelI membrane with SnCl, • 5 日，0 as raw rnaterial through infiltration and low t岱nperature calcination methods in air. The resulting products were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD).τbe results showed that the products prepared from the two biotemplates had high purityand faithfulIy duplicated morphologies of the original templates. Meantime ,the several influential factors on the products inc1 uding t回r l perature of calcination and reactant concentrations were studied.and the synth