脱水污泥-松木共热解生物炭的制备及吸附性能.pdfVIP

INDUSTRIAL WATER WASTEWATER ~;..用水品怠水 Vol.44 No.3 Jun. , 2013 脱水污泥-松木共热解生物炭的制备及吸附性能 成功 1 ，孙蕾2 ，焦李2 ，肖波2 (1.深圳市环境科学研究院，广东 深圳I 518∞1; 2.华中科技大学环境科学与工程学院，武汉 43∞74) 摘要:以脱水污泥(含水率 80%)和松木的混合物为原料共热解制备生物炭。研究了松木掺混比、热解温度对 生物炭产率和 BET 比表面积(Sær) 的影响，采用元素分析、工业分析和扫描电镜比较了单独热解及共热解生物炭 的元素组成和表面形貌。结果表明，生物炭产率随着松木掺混比的增加而提高，随着热解温度的升高而下降。 2 种原料共热解存在明显的协同效果:松木提高了生物炭的碳元素含量，污泥的水分具有一定的活化作用，生物发 2 表面粗糙程度增加、 S町扩大。当松木掺混比为 60%、热解温度为 750 c时，生物炭 Sær 达到最高的 213.4 m，倍。 此外，生物炭对水中苯盼的吸附符合准二级动力学，等i亘吸附过程能用 Freundlich 模型描述。 关键词:脱水污泥;共热解;生物炭;吸附 中圈分类号: X703.5 文献标识码:A 文章编号: 1∞9-2455(2013)03-∞55-05 Preparation of biochar from co-pyrolysis of dewatered sewage sludge-pine sawdust and its adsorption capability 1 2 2 CHENG Gong , SUN Lei , JIAO Li , XIAO B02 (1. Shenzhen Academy 01Environmental Science , Shenzhen 518，ω1， China; 2. School 01Environmental Science and Engineeπ晤; Huazhong University 01 Science and Technology, Wuhan 43ω74， China) Abstract: Blends of dewatered sewage sludge(moisture content was 80%) and pine sawdust were used as feed stocks for biochar preparation from co-pyrolysis. The effects of blending ratio of pine sawdust and pyrolysis temperature on yield and Sær of biochar were studied; furthermore , the element composition and surface topogra- phy of biochars prepared from pyrolysis and co -pyrolysis were compared through ultimate analysis, proximate analysis and SEM. The results showed that , biochar yield increased with the increasing of pine sawdust while de- creased with the increasing of pyrolysis temperature. A