Chapter 5偏晶概要1.pptVIP

液态不混溶合金凝固过程模拟 Characteristics of solidification 2. Experimental research of the solidification of immiscible alloys Rapid solidification 3. Theoretical investigation of liquid-liquid phase transformation Process of liquid-liquid decomposition: 1) Nucleation of droplets 2) Diffusional growth(Ostwald ripening) 3) Stokes and/or Marangoni motion. 4) Collision and coagulation of drops 5) interaction with the solidification front 3.4 Collision and coagulation when the content of Pb is less than 9%, the average droplet radius decreases with cooling rate exponentially according this equation 4.2 Directional solidification of immiscible alloy Continuity equation is the Stokes velocity of droplets, is Marangoni velocity of droplets. Temperature field During the liquid-liquid decomposition, the heat transfers both through diffusion controlled process and the movement of droplets. The temperature field in the sample satisfies Where are the densities of the two phase mixture and the product of monotectic reaction, are the heat capacities of the two phase mixture, the matrix and of the droplet respectively, is the heat conductivity of the two phase mixture, L is the latent heat of solidification, is the volume fraction of the monotectic reaction products. Concentration field is the supersaturation, H is the height of the sample. Fig. The lead concentration after solidification of an Al-5Wt%Pb alloy cooled with three different cooling rates through the miscibility gap. At the lowest cooling rate a layer is formed at the bottom. With increasing cooling rate and thus increasing