28 215-217 转211 食品安全与检测 3+6 三乙酸甘油酯检测方法的研究.pdfVIP

现代食品科技 Modern Food Science and Technology 2010, Vol.26, No.2 三乙酸甘油酯检测方法的研究 孔浩辉，陈翠玲，汪军霞，李峰，程志颖，周瑢，吴君章 （广东中烟工业有限责任公司，广东广州510145 ） 摘要：以乙醇为溶剂，反式茴香脑为内标，并采用极性毛细管柱进行色谱分离，用带FID检测器的气相色谱仪进行检测， 建立了增塑剂中三乙酸甘油酯的内标定量法。结果表明，该方法与 《烟用三乙酸甘油酯》 （YC144- 2008 ）所推荐的定量方法相比较，能够实现烟用三乙酸甘油酯纯度的准确测定。三乙酸甘油酯在质量分数33%-- 110%含量范围，线性回归系数0.999；回收率为95.4%-105% ，RSD均小于1%。与YC/T144- 2008所推荐的归一化法比较，本文所建立的方法可以提高判断产品是否符合要求的准确性，从而减少产品质量上的误判。 关键词：内标法；增塑剂；三乙酸甘油酯 文章篇号:1673-9078(2010)2-215-217 Study on the Detection Method for Triacetin KONG Hao-hui, CHEN Cui-ling, WANG Jun-xia, LI Feng, CHENG Zhi-ying, ZHOU Rong, WU Jun-zhang （China Tobacco Guangdong Industrial Corporation, Guangzhou 510145, China ） Abstract: A quantitative analytical method for triacetin in plasticizer was developed by using Gas chromatography (GC) with a FID detector and a polar capillary. The sample was dissolved in ethanol and trans-anethole was used as internal standard. Results showed that linear relationship between the ratio of peak area and the concentration of triacetin within the range from 33.3% to 110% was obtained with r2 0.999. The average recoveries were between 95.4%-105%, with RSD less than 1%. Compared with the method recommended by YC/T 144, this method was more suitable for checking the quality of product. Keywords: internal standard method; plasticizer; triacetin 215 三乙酸甘油酯是乙酸纤维滤棒的常用增塑 公司）；CP225D型十万分之一天平（感量：0.01 剂，其使用量直接影响到滤棒的硬度、压 mg/80g 、0.1 mg/220g ，德国sartorius公司）。 、缩头等[1- 乙醇（色谱纯，Merck）；反式茴香脑（99.0％ 2] ，进而影响滤棒的过滤效率及卷烟的抽吸质 量。为此，烟草行业2008年颁布实施了 《烟 ，Aldrich）；三乙酸甘油酯（99.2%，Fluka