吸附和扩散参数.pdf

Physics and Chemistry of the Earth 31 (2006) 600–609 /locate/pce Derivation of consistent sorption and diffusion parameters and their uncertainties for compacted MX-80 bentonite M. Ochs a,*, C. Talerico a,1, P. Sellin b, A. Hedin b a BMG Engineering Ltd., Ifangstrasse 11, CH-8952 Schlieren-Zurich, Switzerland ¨ b Swedish Nuclear Fuel and Waste Management Co., Box 5864, SE-102 40 Stockholm, Sweden Received 15 August 2005; received in revised form 25 January 2006 Available online 7 July 2006 Abstract SKB is currently preparing license applications related to the deep repository for spent nuclear fuel and an encapsulation plant. Rec- ommended values for the diffusion-available porosity (e), effective diffusivity (D ) and distribution coefficient (K ), as well as the associ- e d ated uncertainties are derived and documented in a SKB technical report (Ochs, M., Talerico, C., 2004. SR-CAN: Data and uncertainty assessment. Migration parameters for the bentonite buffer in the KBS-3 concept. SKB Technical Report TR-04-18, SKB, Stockholm) for a total of 38 elements and oxidation states. Based on these results, this contribution focuses on issues of consistency and on quantification of the uncertainties associated with each parameter. The importance of consistency is twofold. First, the above parameters a