贮氢合金的制备与电化学性能preparation and electrochemical .pdfVIP

2009 年第67 卷 化 学 学 报 Vol. 67, 2009 第6 期, 513～518 ACTA CHIMICA SINICA No. 6, 513～518 ·研究论文· MgNi-x% TiNi0.5Mn0.5 (x ＝10, 30, 50)贮氢合金的制备与电化学性能 刘素琴* 陈东洋 黄可龙 仲晓玲 ( 中南大学化学化工学院 长沙 410083) 摘要 用机械合金化法成功制备出MgNi 和TiNi0.5Mn0.5 合金, 并将不同质量的TiNi0.5Mn0.5 与MgNi 合金球磨复合10 h 制备MgNi-x% TiNi0.5Mn0.5 (x ＝10, 30, 50)合金. XRD 结果表明球磨后几种合金均为非晶体, TiNi0.5Mn0.5 均匀分散到 MgNi 合金主相中; 充放电结果表明MgNi-TiNi0.5Mn0.5 复合合金的初始容量比纯MgNi 合金(443.12 mAh/g)低, MgNi- 10% TiNi Mn 首次放电容量是394.46 mAh/g, 但循环寿命有较大的改善, 50 次循环后容量保持在232.57 mAh/g, 保 0.5 0.5 持率达 59%; 动电位扫描结果表明复合后合金电极抗腐蚀能力提高; 循环伏安法和电化学阻抗谱法研究结果表明: 复 合后电极表面的电化学催化性能增强, H 原子在合金电极内部的扩散阻抗减小. 关键词 镁基贮氢合金; 电化学性能; 机械合金化; 循环稳定性 Preparation and Electrochemical Properties of MgNi-x% TiNi0.5Mn0.5 (x ＝10, 30, 50) Composite Alloys for Hydrogen Storage Liu, Suqin* Chen, Dongyang Huang, Kelong Zhong, Xiaoling (College of Chemistry Chemical Engineering, Central South University, Changsha 410083) Abstract MgNi alloy and TiNi0.5Mn0.5 alloy were successfully synthesized by a mechanical alloying (MA) approach. The MgNi and TiNi0.5Mn0.5 alloys were mixed to prepare the MgNi-x% TiNi0.5Mn0.5 (x ＝10, 30, 50) alloys by MA for 10 h. The XRD results suggested that the alloys have amorphous structures, and TiNi0.5Mn0.5 alloys have been dissolved in the main phase of the MgNi alloys. The discharge capacity and cycle life of the alloys were tested, showing that the cycle life of the alloys being doped became much better than