用红外光谱和强伸性分析细化羊毛的二级结构转变.pdfVIP

第2O卷第4期 纺 织 高 校 基 础 科 学 学 报 Vo1．20，No．4 2007年 12月 BASIC SCIENCES JOURNAL oF TEXTILE UNIVERSITIES Dec．，2007 Article ID：1006—8341(2007)04—0412—06 Secondary structure analysis of stretched wool using FT—IR and tensile stress—strain curve TANG Fu-jH ，LIU Hong—ling ，YU Wei—dong 。 (1．HYX China(Group)Co．Ltd．．Shanghai 200021．China； 2．College of Textiles，Donghua University，Shanghai 201620，China； 3．College of Textile，Wuhan University of Science and Engineering，Wuhan 430073，China) Abstract：The microstructure transformation of wool fibers is expored．IR spectra and tensile stress—strain curve are used to analyze the stretching behavior and conformation of wool fiber with different stretching rates．It is found that the breaking stress increases，while the break— ing elongation decrease with the increase of stretching rate(30 9／6，50 ，70 ，90 ，110 9／5)of wool fiber．In the method，there is 52 yield elongation left for 1 1 0 stretching rate．Based on the analysis of Sulphonate bond(S—O)and amide I and amide Ill in IR as well as the com— parison of mechanic properties，it can be concluded that it exists not only the structural trans— formation from a—helix to B—sheet，but also structural slippage of wool fiber during stretching． Key words：stretched wool fiber；FT—IR；stress—strain curve；secondary structure CLC Number：TS 102．311 Document Code：A 0 Introduction Wool fineness is one of the important parameters to determine softness and handle·which affect the salability and profit of end—use products as well as its application．Sheep breeding method is effective in cultivating sheep that can produce finer wool fiber，however，its amount of wool fiber is limited[ ． Thereof，it necessitates the development of