弱碱性土有效硫测定影响因素的探讨.pdfVIP

2011 年4 月 岩矿测试 Vo 1.30 , No. 2 Apri120l 1 ROCK AND MIN应民AL ANALYSIS 182 阳 185 文章编号: 0254 -5357(201 1) 02 一 0182 一 04 弱碱性=1::有效硫测寇影响因亲的探讨 刘婷琳，马名扬\胡耀罔，彭四清 (广东省生态环境与土壤研究所，广东广州 510650) 捕望:准确圳定土壤中有效硫的含章，对土壤硫元素是否缺边的判定~合攻施用硫肥具有重要的意义。测定碱 性土中有效硫的合景可以采用 pH =8.5 的碳瞰虱纳没提后圳定没提液中碗的含囊。文章采用破瞰氮纳法浸提 弱碱性土中的有效硫，紫外-可见分先尤皮法测定，针对影响硝碱性土中有效硫测定过程中没提坡的氧化脱色，、 比浊域的酸皮条件等影响因素进行了详细探讨。结果表明，在 20 - 25 c提取条件下有效硫测定值基本一敢，而 30 c提取条件下样品测定值有偏高的趋势;比浊液的酸度选择盐酸的加入量大于1.5 mL，制定精度高，或性好。 方法回收...为 96.6% -104.6% ;对于土壤中 6 -25 mg/kg 有效疏的测定，标准偏差为0.110 -0.271 mgl峙，变异 系数均 5% 。建立的方法快速、简便、准确，重复性和再现性较好，适用于各种类型崩碱性土壤中有效碗的分析 检测工作。 提键调:有效硫;弱碱性土;影响因素 中圈分类号: 515 1. 93; 0613.51 文献标识明:B A Discussion on the Effect Factors of Available Sulphur Determination in Weak Alkaline Soils UU Ting-lin , MA Ming-yang * , HU fjωψω， PENG Siqing (Guangdong Institute of Eco帽environmental and Soil Science , Guangzhou 510650 , China) Abstract: The high precision data of 5 concentration in top soil is an important proxy to estimate the sulphur loss in top soil. A discussion is presented in this paper on the effect factors of available sulphur determination in weak alkaline soil with pH =8. 5 sodium bicarbonate extractants. A further study was made on the oxidizing discoloring of extractive solution and the acidity of turbidimetry solution during the determination process. The results indicated the reliable data were obtained in the temperature range of 20 C to 24 C , but the analytical data were higer if the temperature was higher than 30 C.叽le recovery of this method was 96.6% -104.6% ,the standard deviation was O. 110-0 .271 mglkg , and a relative standard deviation of 5 % if the 5 concentration is between 6♂5 mglkg in top soil. The method has the advantage of being fast , simple , accurate and hi