外源硫酸盐对武汉南湖表层沉积物磷形态的作用.pdf

2012,32(4) 666~673 China Environmental Science 1,2 1* 1 1 1 , , , , (1. , 430070 2. , 253034) ,,., ,(TP)(SRP), . ,(AVS),.pH ,Eh . ,(Ca2P),(FeP) 800mg/kg , 51.4%~56.6%,(P0.01),.TPSRP . (OFeP)(P 0.05),. (AVS) X524 A 2012 Effect of external sulfate on fraction of phosphorus in the surface sediment from Lake Nanhu in Wuhan. YUAN Tan1,2 1* 1 1 1 , HUA Yu-mei , ZHU Duan-wei , DING Min , CAI Jian-bo (1.College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China 2.Dezhou Environmental Monitoring Central Station, Dezhou 253034, China). China Environmental Science, 2012,32(4)666~673 Abstract The response of phosphorus fraction in the sediments from Lake Nanhu in Wuhan to the input of sulfate was investigated based on the indoor simulation experiments. It showed that sulfate input improved the mobility of phosphorus in sediments, resulting in the increase of concentrations of total phosphorus (TP) and soluble reactive phosphorus (SRP) in the overlying water. Higher external sulfate concentration experienced greater increase of phosphorus contents in the overlying water. The contents of acid volatile sulfur (AVS) in the sediments initially increased and then fell, while the chromium reducible sulfur kept the trend of increase. It indicated that the AVS in the sediments was produced after the sulfate penetrated to the sediments, followed by the transformation of AVS to chromium reducible sulfur. pH increased and Eh decreased due to the reduction of sulfate in the sediments. The effect of sulfate input was much different for the different fractions of phosphorus in the sediments. The contents of Ca2-P increased with the increase of sulfate concentration. The F