酸处理对秸秆基活性炭电化学性能的影响 - ingenta connect.pdf

· 596 · 硅 酸 盐 学 报 2011 年 第39 卷第4 期 硅 酸 盐 学 报 Vol. 39 ，No. 4 2 0 1 1 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2011 酸处理对秸秆基活性炭电化学性能的影响 1,2 1,2 1 肖正辉 ，李学良 ，邢高瞻 (1. 合肥工业大学化学工程学院，合肥 230009 ；2. 可控化学与材料化工安徽省重点实验室，合肥 230009) 摘 要：以生物质秸秆炭化物为基础炭材料，采用无机酸处理，除去其中的硅酸盐组分，制备超级电容器用活性炭。利用扫描电镜及能谱分析和红外 吸收光谱表征了反应前后活性炭的结构及组分变化。利用循环伏安方法考察了活性炭处理前后的电化学性能。结果表明：酸处理可溶去炭材料中的无 机组分，处理后活性炭中硅含量明显减少；无机组分的除去有利于炭材料形成更丰富的孔结构，为电解液提供输运通道，导致炭材料比电容加大，循 环伏安曲线显示出良好的可逆特性；随着处理时间延长，超级炭材料的比电容逐步加大，最高比电容达426.3 F/g ，比原样炭提高了50% 以上，活性炭 循环3 000 次后的比电容仍保持97.2% 。 关键词：活性炭；超级电容器；电极材料；比电容；电能储存 中图分类号：TQ424.1 文献标志码：A 文章编号：0454–5648(2011)04–0596–05 Effects of Acidic Solution Treatment on Electrochemical Performance of Straw Based Activated Carbon XIAO Zhenghui ，LI Xueliang ，XING Gaozhan (School of Chemical Engineering, Hefei University of Technology, Hefei 230009; Anhui Key Laboratory of Controllable Chemistry Reaction and Material Chemical Engineering, Hefei 230009, China) Abstract: An activated carbon material for electrical energy storage was prepared via the treatment of straw-based carbon with acidic solution. The structures and compositions of the treated carbon were characterized by scanning electron microscope-energy dispersive spectrometer and Fourier transform infrared spectrophotometer. The effect of acidic solution treatment on the electrochemical per- formance of the carbon was investigated by cyclic voltammetry. The results show that the acidic solution treatment causes the disso- lution of inorganic substance and the de