论文与专利写作期中报告.pdfVIP

南臺科技大學 化學工程與材料工程學系 論文與專利寫作 期中報告 班級：碩研化材一甲 姓名：陳廷睿 學號：MA440206 授課老師：林鴻儒 教授 不對稱的聚砜中空纖維膜接觸氣對二氧化碳吸收的開發 ABSTRACT (M)Porous asymmetric polysulfone (PSf) hollow fiber membranes were fabricated via wet spinning process. A mixture of 1-methyl-2-pyrrolidone (NMP) and distilled water (90 wt.% NMP) was used as bore fluid to make hollow fiber membranes without inner skin layers, whereas glycerol with 2 and 4 wt.% was used as additives to the spinning dope. (I)The effect of the additives concentration on the structure, surface porosity, pore size, critical water entry pressure (CEPw), and CO2 absorption flux of the fabricated membranes were investigated. The cross-section and inner surface of the membranes were examined via scanning electronic microscopy (SEM). (R)Using glycerol as the additive in the spinning dope provided the membrane structure with a thin finger-like and a thick sponge-like layer, which resulted in a high CEPw and CO2 absorption rate. Results of gas permeation tests showed with increasing glycerol concentration the N2 permeance increase significantly and the wetting resistance decrease slightly. CO2 absorption by distilled water was conducted through the gas– liquid membrane contactors. (D)By using 4% glycerol in the spinning dope, the PSf membrane showed a CO2 flux of approximately 57% higher than the PSf membrane with 2% glycerol at the absorbent flow rate of 200 ml/min. (M) 多孔非對稱聚砜（PSF ）中空纖維膜通過濕紡絲方法製造。1- 甲基-2-吡咯烷酮（NMP ） 和蒸餾水（90 重量％的NMP ）的混合物被用作孔流體，使無內表層的中空纖維膜，而甘油，2 和4 ％（重量）用作添加劑加入到紡絲原液。 (I) 添加劑濃度的結構，表面孔隙率，孔徑，臨界水入口壓力（CEPw ），以及所製造的膜的 CO 2 吸收磁通的影響進行了研究。膜的橫截面和內表面分別通過掃描電子顯微鏡檢查 （SEM ） (R) 使用甘油作為在用薄指狀和厚的海綿狀層，這導致了高CEPw 和CO 2 吸收速率提供的膜 結構的紡絲原液的添加劑。氣體滲透測試結果表明：用蒸餾水CO 2 吸收通過氣體 - 液體膜接 觸進行與甘油濃度的增加氮氣滲透性顯著增加和潤濕電阻降低略。 (D) 通過在紡絲原液用4 ％甘油，在PSF 膜顯示出比與在200 毫升/分鐘的吸收劑流量的2 ％甘 油的聚砜膜高出約57 ％的CO 2 通量。