具有可见光光催化活性n 掺杂纳米二氧化钛的制备和表征 - 中南大学学报.pdfVIP

第 40 卷第 4 期 中南大学学报( 自然科学版) Vol.40 No.4 2009 年 8 月 Journal of Central South University (Science and Technology) Aug. 2009 具有可见光光催化活性N 掺杂纳米二氧化钛的制备和表征 彭 兵，刘立强，齐萨仁，柴立元，刘云超，李国良 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：以廉价的TiOSO4 为原料，通过水解法制备正钛酸前驱体，然后，向正钛酸前驱体中加入尿素作为氮源， 经煅烧制备氮掺杂纳米二氧化钛。用 X 射线衍射、紫外−可见吸收光谱、热重−差热分析和 X 射线光电子能谱等 方法对制备的样品进行表征，考察煅烧温度、煅烧时间及 Ti 与 N 配比等对光催化活性的影响。研究结果表明： 制备的样品均为锐钛矿，氮掺杂使二氧化钛在可见光区的光吸收明显增强；煅烧温度和 Ti 与 N 配比对光催化性 能影响显著；于 400 ℃制备的样品中存在 1 个最佳的 Ti 与 N 配比，所对应的可见光催化活性最强，甲基橙降解 实验 15 min 时脱色率达到 97% 。 关键词：硫酸氧钛；氮掺杂 TiO2 ；尿素；可见光；光催化 中图分类号：TQ134.11 文献标识码：A 文章编号：1672−7207(2009)04−0944−06 Preparation and characterization of N-doped TiO2 nano-powder with visible light photocatalytic activity PENG Bing, LIU Li-qiang, QI Sa-ren, CHAI Li-yuan, LIU Yun-chao, LI Guo-liang (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The nano-meter particle of TiO precursor was prepared by hydrolysis with industrial titanic solution, and then 2 urea was added as the source of nitrogen. The mixture was calcined to obtain N-doped TiO2 . The prepared samples were then characterized using X-ray diffractrometry, UV-Vis absorption spectra, TG-DTA and X-ray photoelectron spectroscopy. The effects of calcination temperature, time and mole ratio of Ti to N on the photocatalytic activity were investigated. The results show that all catalysts are anatase, and the doping of nitrogen leads to an obvious increase in optical absorption intensity in the visible-light region. The calcination temperature and mole ratio of