微孔-介孔多级孔炭材料的制备及电化学电容性能研究preparation of .pdfVIP

2009 年第 67 卷 化 学 学 报 Vol. 67, 2009 第 13 期, 1430～1436 ACTA CHIMICA SINICA No. 13, 1430～1436 ·研究论文· 微孔-介孔多级孔炭材料的制备及电化学电容性能研究 邢 伟 禚淑萍* 高秀丽 黄丛聪 ( 山东理工大学化学工程学院 淄博 255049) 摘要 采用有机-有机自组装法, 并结合后活化法制备了一类具有微孔-介孔复合孔结构的多级孔炭材料(HPC), 并研 究了这类材料的电化学电容性能. 孔结构测试表明, 采用 KOH 后活化法可以在介孔炭的孔壁上控制性地生成微孔. 电 化学测试表明, 与文献中报道的硬模板法制备的介孔炭相比, HPC 具有更好的电化学电容性能. 在 100 mV/s 的快速电 压扫描速率下, 它的比电容值能达到 168.9 F/g. 更值得指出的是, HPC 的高频电容性能非常优异, 在 1 Hz 时的比电容值 高达 180 F/g, 这一数值优于任何其它类的电极材料. HPC 优异的电化学电容性能应当归功于它特殊的多级孔结构, 有 助于电解质离子在孔道内的快速扩散. 关键词 微孔; 介孔; 多孔炭; 电化学电容器; 能量密度 Preparation of Micro-meso Hierarchical Porous Carbon and Studies in Its Electrochemical Capacitive Performances Xing, Wei Zhuo, Shuping* Gao, Xiuli Huang, Congcong (School of Chemical Engineering, Shandong University of Technology, Zibo 255049) Abstract A kind of micro-meso hierarchical porous carbon (HPC) was prepared by a combination of or- ganic-organic self-assembly approach and post-activation approach, and also investigated as an electrode material in electrochemical capacitors. Pore structure analysis shows that micropores can be adjustably gen- erated on the mesopore wall of mesoporous carbon (MC) by post activation at high temperature using KOH as an activating agent. As evidenced by electrochemical measurements, HPC shows superior capacitive be- havior (exhibiting a high capacitance of up to 168.9 F/g even at a very high sweep rate of 100 mV/s) to hard-templated carbon reported in the literature. Of