金属有机骨架材料(MOFs).pptx

Metal–Organic Frameworks ;;CONTENTS;Introduction;;;;Stability of metal–organic frameworks;;Chemical stability;1;The chemical (acid–base) stability of some representative metal–organic frameworks based on literature data. The bar length indicates the pH range that the metal–organic frameworks (MOFs) can tolerate. An arrow indicates that the MOF can withstand pH0 or pH14. ;Selected sections of representative metal–organic framework materials a | ZIF-8 b | Cu-BTTri c | MIL-53(Al) d | MIL-101(Cr) e | PCN-426-Cr(iii) f | [(CH3)2NH2]2 [Eu6 (μ3- OH)8(1,4-NDC)6(H2O)6].;Connectivity of Zr6 nodes in zirconium-based metal–organic frameworks and the associated carboxylate molecules required to link nodes together. ;2;3;4;MOF stability in catalytic systems;;Solution-phase catalysis;1;Catalytic oxidation of water using Ir-containing derivatives of UiO-67. The image shows the structure of UiO-67 and Ir-containing linkers 1 and 2 that are utilized for water oxidation catalysis at pH 1. ;Catalytic hydrolysis of the nerve agent soman (known as GD) by NU-1000;2;Oxidative dehydrogenation of cyclohexene to benzene using V-UiO-66 as a catalyst;Future perspectives;The extended mechanical and chemical stabilities of MOFs in thin-film form are also attractive goals.;Thanks!